Conductance in homomorphous solvents: Tetrabutylammonium salts and alkali picrates in butyrolactone-sulfolane mixtures

Conductance measurements are reported for LiPi, NaPi, KPi, RbPi, CsPi, Bu₄NPi, Bu₄NBr, Bu₄NClO₄, Bu₄NNO₃, and Bu₄NBBu₄ at 25°C in -butyrolactone-sulfolane mixtures. In these mixtures of solvents that are practically homomorphous, isodielectic and with comparable dipole moments, the ion pair association and ionic mobilities of large ions conform to the expectations of the primitive model. Electrolytes containing lithium or sodium ions show anomalies indicating that other factors besides shape, dipole moment, and polarizability of the solvent molecules are involved in the association and transport processes of these ions.     

Ion-pair high-performance liquid chromatographic separation of a multicomponent anticholinergic drug formulation

N,N'-Trimethylene-bis-(pyridinium-4-aldoxime)dibromide, 4-pyridine aldoxime, atropine sulfate, benactyzine hydrochloride, methyl paraben and propyl paraben are separated by ion-pair high-performance liquid chromatography. The method is specific for detecting and quantifying each compound in a complex mixture without solvent extraction or pretreatment. Levels as low as 1 ng on column are quantifiable by the procedure. All components are eluted within 9 min subsequent to the initial injection. Because of the simplicity of the method, the procedure is suitable for routinely monitoring the stability of the various compounds in the formulation during storage.     

NEW METHOD FOR LOW ORDER SPECTRAL MODEL AND ITS APPLICATION

In order to overcome the deficiency in classical method of low order spectral model, a new method for low order spectral model was advanced. Through calculating the multiple correlation coefficients between combinations of different functions and the recorded data under the least square criterion, the truncated functions which can mostly reflect the studied physical phenomenon were objectively distilled from these data. The new method overcomes the deficiency of artificially selecting the truncated functions in the classical low order spectral model. The new method being applied to study the inter-annual variation of summer atmospheric circulation over Northern Hemisphere, the truncated functions were obtained with the atmospheric circulation data of June 1994 and June 1998. The mechanisms for the two-summer atmospheric circulation variations over Northern Hemisphere were obtained with two-layer quasi-geostrophic baroclinic equation.     

APPLICATION OF VARIABLE-FIDELITY MODELS TO AERODYNAMIC OPTIMIZATION

For aerodynamic shape optimization, the approximation management framework (AMF) method is used to organize and manage the variable-fidelity models. The method can take full advantage of the low-fidelity, cheaper models to concentrate the main workload on the low-fidelity models in optimization iterative procedure. Furthermore, it can take high-fidelity, more expensive models to monitor the procedure to make the method globally convergent to a solution of high-fidelity problem. Finally, zero order variable-fidelity aerodynamic optimization management framework and search algorithm are demonstrated on an airfoil optimization of UAV with a flying wing. Compared to the original shape, the aerodynamic performance of the optimal shape is improved. The results show the method has good feasibility and applicability.     

NONLINEAR VIBRATION OF CIRCULAR SANDWICH PLATES UNDER CIRCUMJACENT LOAD

Based on von Karman plate theory, the issue about nonlinear vibration for circular sandwich plates under circumjacent load with the loosely clamped boundary condition was researched. Nonlinear differential eigenvalue equations and boundary conditions of the problem were formulated by variational method and then their exact static solution can be got. The solution was derived by modified iteration method, so the analytic relations between amplitude and nonlinear oscillating frequency for circular sandwich plates were obtained. When circumjacent load makes the lowest natural frequency zero, critical load is obtained.     

STATISTIC MODELING OF THE CREEP BEHAVIOR OF METAL MATRIX COMPOSITES BASED ON FINITE ELEMENT ANALYSIS

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THE TRANSIENT ELLIPTIC FLOW OF POWER-LAW FLUID IN FRACTAL POROUS MEDIA

1　ＴｈｅＦｌｏｗＭｏｄｅｌｏｆＰｏｗｅｒ＿ＬａｗＦｌｕｉｄｉｎＲａｄｉｃａｌＦｒａｃｔａｌＲｅｓｅｒｖｏｉｒＴｈｅｔｒａｎｓｉｅｎｔｆｌｏｗｏｆｐｏｗｅｒ＿ｌａｗｆｌｕｉｄｉｎｒａｄｉｃａｌｆｒａｃｔａｌｒｅｓｅｒｖｏｉｒｉｓｓｔｕｄｉｅｄｉｎＲｅｆ.[1 ] ,ａｎｄａｎａｌｙｔｉｃａｌｓｏｌｕｔｉｏｎｏｆＬａｐｌａｃｅｓｐａｃｅｉｓｄｅｒｉｖｅｄ .ＩｎＲｅｆ.[2 ] ,ｔｈｅｔｒａｎｓｉｅｎｔｅｌｌｉｐｔｉｃａｌｆｌｏｗｉｓｒｅｓｅａｒｃｈｅｄｏｎｍｏｄｅｌｏｆｅｘｐａｎｄｉｎｇｒｅｃｔａｎｇｌｅ .Ｔ…     

SELF-ADAPTIVE STRATEGY FOR ONE-DIMENSIONAL FINITE ELEMENT METHOD BASED ON ELEMENT ENERGY PROJECTION METHOD

Based on the newly-developed element energy projection (EEP) method for computation of super-convergent results in one-dimensional finite element method (FEM), the task of self-adaptive FEM analysis was converted into the task of adaptive piecewise polynomial interpolation. As a result, a satisfactory FEM mesh can be obtained, and further FEM analysis on this mesh would immediately produce an FEM solution which usually satisfies the user specified error tolerance. Even though the error tolerance was not completely satisfied, one or two steps of further local refinements would be sufficient. This strategy was found to be very simple, rapid, cheap and efficient. Taking the elliptical ordinary differential equation of second order as the model problem, the fundamental idea, implementation strategy and detailed algorithm are described. Representative numerical examples are given to show the effectiveness and reliability of the proposed approach.     

ANALYSIS OF THE LOCALIZATION OF DAMAGE AND THE COMPLETE STRESS-STRAIN RELATION FOR MESOSCOPIC HETEROGENEOUS ROCK UNDER UNIAXIAL TENSILE LOADING

The mechanical behavior of rock under uniaxial tensile loading is different from that of rock under compressive loads. A micromechanics-based model was proposed for mesoscopic heterogeneous brittle rock undergoing irreversible changes of their microscopic structures due to microcrack growth. The complete stress-strain relation including linear elasticity, nonlinear hardening, rapid stress drop and strain softening was obtained. The influence of all microcracks with different sizes and orientations were introduced into the constitutive relation by using the probability density function describing the distribution of orientations and the probability density function describing the distribution of sizes. The influence of Weibull distribution describing the distribution of orientations and Rayleigh function describing the distribution of sizes on the constitutive relation were researched. Theoretical predictions have shown to be consistent with the experimental results.     

GENERAL SOLUTION OF THE OVERALL BENDING OF FLEXIBLE CIRCULAR RING SHELLS WITH MODERATELY SLENDER RATIO AND APPLICATIONS TO THE BELLOWS (Ⅳ)-CALCULATION FOR U-SHAPED BELLOWS

This is one of the applications of Part (I), in which the angular stiffness, and the corresponding stress distributions of U-shaped bellows were discussed. The bellows was divided into protruding sections, concave sections and ring plates for the calculation that the general solution (I) with its reduced form to ring plates were used respectively, but the continuity of the surface stresses and the meridian rotations at each joint of the sections were entirely satisfied. The resent results were compared with those of the slender ring shell solution proposed earlier by the authors, the standards of the Expansion Joint Manufacturers Association (EJMA), the experiment and the finite element method. It is shown that the governing equation and the general solution (I) are very effective. Contributed by HUANG Qian Biography: ZHU Wei-ping (1962-)